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Supplement of Geosci. Model Dev., 9, , doi: /gmd supplement Author(s) CC Attribution 3.0 License. Supplement of D-region

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Supplement of Geosci. Model Dev., 9, , doi: /gmd supplement Author(s) CC Attribution 3.0 License. Supplement of D-region ion neutral coupled chemistry (Sodankylä Ion Chemistry, SIC) within the Whole Atmosphere Community Climate Model (WACCM 4) WACCM-SIC and WACCM-rSIC Tamás Kovács et al. Correspondence to: Tamás Kovács The copyright of individual parts of the supplement might differ from the CC-BY 3.0 licence. Number 1 Reaction 2,3 A4 n E 5 Source[1] 6 Comments, recommendations RPE(1) O + + e - O + hv RPE(2) O e - 2O [2] temperature range of K RPE(3) O e - 2O Temperature interval is uncertain. RPE(4) N + + e - N + hv RPE(5) N e - N + N( 2 D) [2] RPE(6) NO + + e - N + O [2] RPE(7) NO + + e - N( 2 D) + O [2] RPE(8) NO + (N 2 ) + e - NO + N [3] RPE(9) NO + (CO 2 ) + e - NO + CO [3] RPE(10) NO + (H 2 O) + e - NO + H 2 O [3] RPE(11) NO + (H 2 O) 2 + e - NO + 2H 2 O [4] RPE(12) NO + (H 2 O) 3 + e - NO + 3H 2 O [4] RPE(13) NO + (H 2 O)(N 2 ) + e - NO + H 2 O + N [4] RPE(14) NO + (H 2 O)(CO 2 ) + e - NO + H 2 O + CO [4] RPE(15) NO + (H 2 O) 2 (N 2 ) + e - NO + 2H 2 O + N [4] RPE(16) NO + (H 2 O) 2 (CO 2 ) + e - NO + 2H 2 O + CO RPE(17) O 2 + (H2 O) + e - O 2 + H 2 O [4] RPE(18) H 3 O + (OH) + e - OH + H + H 2 O [4] RPE(19) H + (H 2 O) + e - H + H 2 O [5, 6] RPE(20) H + (H 2 O) 2 + e - H + 2H 2 O [6] RPE(21) H + (H 2 O) 3 + e - H + 3H 2 O [6] RPE(22) H + (H 2 O) 4 + e - H + 4H 2 O [7] RPE(23) H + (H 2 O) 5 + e - H + 5H 2 O [6] temperature range of K. temperature range of K. temperature range of K. Not studied. Only estimated from NO + (NO) recombination based on Petrignani et al.[3] Not studied. Only estimated from NO + (NO) recombination based on Petrignani et al.[3] Not studied. Only estimated from NO + (NO) recombination based on Petrignani et al.[3] Data for all NO + water cluster ion reactions is estimated only for T=300K. Not studied. Assumed to be the same as for NO + (H 2O) 2(N 2). Not studied. Assumed to be the same as for O + 4. Not studied. Assumed to be the same as for H + (H 2O) 2. Rate coefficients for all H + (H 2O) n (n=1,...,6) cluster recombination were calculated over the temperature range of K. For larger clusters at 298K. RPE(24) H + (H 2 O) 6 + e - H + 6H 2 O [6] RPE(25) H + (H 2 O) 7 + e - H + 7H 2 O [6] RPE(26) H + (H 2 O) 8 + e - H + 8H 2 O [6] RPE(27) H + (H 2 O) 2 (CO 2 ) + e - H + 2H 2 O + CO RPE(28) H + (H 2 O) 2 (N 2 ) + e - H + 2H 2 O + N RPE(29) H + (H 2 O)(CO 2 ) + e - H + H 2 O + CO Not studied. Assumed to be the same as for H + (H 2O) 3. Not studied. Assumed to be the same as for H + (H 2O) 3. Not studied. Assumed to be the same as for H + (H 2O) 3. RPE(30) O 2 + N 2 + e - O N Temperature interval is uncertain. RPE(31) O 3 + e - O - + O Temperature interval is uncertain. RPE(32) 2O 2 + e - O O Temperature interval is uncertain. PIR(1) O + + O 2 O O [8] Rate coefficient was measured over the range of K. PIR(2) O + + N 2 NO + + N Temperature interval is uncertain. PIR(3) O + + N( 2 D) N + + O PIR(4) O + + NO NO + + O PIR(5) O NO NO + + O PIR(6) O N 2 NO + + NO PIR(7) O O 2 + M O M [9] PIR(8) O H 2 O + M O 2 + (H2 O) + M PIR(9) O N 2 + M O 2 + (N2 ) + M [10] PIR(10) O N NO + + O PIR(11) O N( 2 D) N + + O Rate coefficient was measured only for M=O 2 over the range of K. Rate coefficient was measured only for M=N 2 over the range of K PIR(12) O 2 + (H2 O) + H 2 O H 3 O + (OH) + O [11] Rate coefficient was measured at 296K. PIR(13) O 2 + (H2 O) + H 2 O H + (H 2 O) + OH + O [11] Rate coefficient was measured at 296K. PIR(14) O 2 + (H2 O) + N 2 + M O 2 + (H2 O)(N 2 ) + M PIR(15) O 2 + (N2 ) + O 2 O N PIR(16) O 2 + (N2 ) + M O N 2 + M Temperature interval is uncertain. PIR(17) O 2 + (N2 ) + CO 2 O 2 + (CO2 ) + N [12] Not studied. Based on estimation only. PIR(18) O 2 + (CO2 ) + H 2 O O 2 + (H2 O) + CO [12] Not studied. Based on estimation only. PIR(19) O 2 + (H2 O)(N 2 ) + CO 2 O 2 + (H2 O)(CO 2 ) + N [12] Not studied. Based on estimation only. PIR(20) O 2 + (H2 O)(N 2 ) + M O 2 + (H2 O) + N 2 + M PIR(21) O 2 + (H2 O)(CO 2 ) + H 2 O O 2 + (H2 O) 2 + CO PIR(22) O 2 + (H2 O)(CO 2 ) + H 2 O H 3 O + (OH)(CO 2 ) + O PIR(23) O 2 + (H2 O) 2 + H 2 O H 3 O + (OH)(H 2 O) + O PIR(24) O O 2 ( 1 D g ) O O [13] Not studied, based on estimation only PIR(25) O H 2 O O + 2 (H2 O) + O [14] Rate coefficient was measured at 300K. Uncertainty of measurement 50%. PIR(26) O O O O Uncertainty of data 67%. PIR(27) O M O O 2 + M Rate coefficient was measured only for 0 0 [15] M=N 2for 297K. PIR(28) N + + O 2 NO + + O [16, 17] PIR(29) N + + O 2 O N [16, 17] PIR(30) N + + O 2 O + + NO [16, 17] PIR(31) N + + O O + + N [16, 17] PIR(32) N + + O 2 O N( 2 D) PIR(33) N O NO + + N( 2 D) [18] PIR(34) N O N + + NO [18] PIR(35) N O 2 O N PIR(36) N NO NO + + N PIR(37) NO + + N 2 + M NO + (N 2 ) + M [10] PIR(38) NO + + CO 2 + M NO + (CO 2 ) + M [10] PIR(39) NO + + H 2 O + M NO + (H 2 O) + M [19] Rate coefficient measured at (295±5)K with 40% error Rate coefficient at measured at (295±5)K with 40% error Rate coefficient was measured only for M=N 2 over the range of K Rate coefficient was measured only for M=N 2 over the range of K Measured only for M=He over the temperature range of K. PIR(40) NO + (N 2 ) + CO 2 NO + (CO 2 ) + N [12] Not studied. Based on estimation only. PIR(41) NO + (N 2 ) + H 2 O NO + (H 2 O) + N [12] Not studied. Based on estimation only. PIR(42) NO + (N 2 ) + M NO + + N 2 + M Measured only for M=He over the temperature range of K PIR(43) NO + (CO 2 ) + H 2 O NO + (H 2 O) + N [12] Not studied. Based on estimation only. PIR(44) NO + (CO 2 ) + M NO + + CO 2 + M [4] Measured only for M=He over the temperature range of K PIR(45) NO + (H 2 O) + HO 2 H + (H 2 O) + NO [11] Data is only upper limit estimation. PIR(46) NO + (H 2 O) + OH H + (H 2 O) + NO Data is only upper limit estimation. Uncertainty of data: 30% PIR(47) NO + (H 2 O) + H H + (H 2 O) + NO Data is only upper limit estimation. Uncertainty of data: 30% PIR(48) NO + (H 2 O) + H 2 O + M NO + (H 2 O) 2 + M [19] Measured for M=He over the temperature range of K with 40% error. PIR(49) NO + (H 2 O) + N 2 + M NO + (H 2 O)(N 2 ) + M [19] PIR(50) NO + (H 2 O) + CO 2 + M NO + (H 2 O)(CO 2 ) + M [19] PIR(51) NO + (H 2 O) 2 + H 2 O + M NO + (H 2 O) 3 + M [19] PIR(52) NO + (H 2 O) 2 + N 2 + M NO + (H 2 O) 2 (N 2 ) + M PIR(53) NO + (H 2 O) 2 + CO 2 + M NO + (H 2 O) 2 (CO 2 ) + M PIR(54) NO + (H 2 O) 3 + H 2 O H + (H 2 O) 3 + HNO [19] Measured for M=He over the temperature range of K with 40% error. Measured for M=N 2 over the temperature range of K. Measured for M=He over the temperature range of K with 40% error. Measured for M=He over the temperature range of K. Measured for M=N 2 over the temperature range of K. PIR(55) NO + (H 2 O)(N 2 ) + H 2 O NO + (H 2 O) 2 + N [12] Not studied. Based on estimation only. PIR(56) NO + (H 2 O)(N 2 ) + CO 2 NO + (H 2 O)(CO 2 ) + N [4] PIR(57) NO + (H 2 O)(N 2 ) + M NO + (H 2 O) + N 2 + M [4] Not studied. Based on estimation only. PIR(58) NO + (H 2 O)(CO 2 ) + H 2 O NO + (H 2 O) 2 + CO [12] Not studied. Based on estimation only. PIR(59) NO + (H 2 O)(CO 2 ) + M NO + (H 2 O) + CO 2 + M [4] Not studied. Based on estimation only. PIR(60) NO + (H 2 O) 2 (N 2 ) + H 2 O NO + (H 2 O) 3 + N [12] Not studied. Based on estimation only. PIR(61) NO + (H 2 O) 2 (N 2 ) + CO 2 NO + (H 2 O) 2 (CO 2 ) + N [4] PIR(62) NO + (H 2 O) 2 (N 2 ) + M NO + (H 2 O) 2 + N 2 + M [4] Not studied. Based on estimation only. PIR(63) NO + (H 2 O) 2 (CO 2 ) + H 2 O NO + (H 2 O) 3 + CO [12] Not studied. Based on estimation only. PIR(64) NO + (H 2 O) 2 (CO 2 ) + M NO + (H 2 O) 2 + CO 2 + M Not studied. Based on estimation only. PIR(65) H + (H 2 O) + H 2 O + M H + (H 2 O) 2 + M [20] Measured for M=O 2 over the temperature range of K with 50% error. PIR(66) H + (H 2 O) + CO 2 + M H + (H 2 O)(CO 2 ) + M [21, 22] temperature range of K PIR(67) H + (H 2 O) + N 2 + M H + (H 2 O)(N 2 ) + M [21, 22] temperature range of K PIR(68) H + (H 2 O) 2 + M H + (H 2 O) + H 2 O + M [21, 22] temperature range of K PIR(69) H + (H 2 O) 2 + H 2 O + M H + (H 2 O) 3 + M [21, 22] temperature range of K PIR(70) H + (H 2 O) 2 + CO 2 + M H + (H 2 O) 2 (CO 2 ) + M [21, 22] temperature range of K PIR(71) H + (H 2 O) 2 + N 2 + M H + (H 2 O) 2 (N 2 ) + M [21, 22] temperature range of K PIR(72) H + (H 2 O) 3 + M H + (H 2 O) 2 + H 2 O + M [21, 22] temperature range of K PIR(73) H + (H 2 O) 3 + H 2 O + M H + (H 2 O) 4 + M [21, 22] temperature range of K PIR(74) H + (H 2 O) 4 + M H + (H 2 O) 3 + H 2 O + M [21, 22] temperature range of K PIR(75) H + (H 2 O) 4 + H 2 O + M H + (H 2 O) 5 + M [21, 22] temperature range of K PIR(76) H + (H 2 O) 5 + M H + (H 2 O) 4 + H 2 O + M [21, 22] PIR(77) H + (H 2 O) 5 + H 2 O + M H + (H 2 O) 6 + M [21, 22] temperature range of K temperature range of K PIR(78) H + (H 2 O) 6 + M H + (H 2 O) 5 + H 2 O + M [4] Not studied. Based on estimation only. PIR(79) H + (H 2 O) 6 + H 2 O + M H + (H2O)7 + M [4] Not studied. Based on estimation only. PIR(80) H + (H 2 O) 7 + M H + (H 2 O) 6 + H 2 O + M [4] Not studied. Based on estimation only. PIR(81) H + (H 2 O) 7 + H 2 O + M H + (H 2 O) 8 + M [4] Not studied. Based on estimation only. PIR(82) H + (H 2 O) 8 + M H + (H 2 O) 7 + H 2 O + M [4] Not studied. Based on estimation only. PIR(83) H + (H 2 O) 2 (CO 2 ) + H 2 O H + (H 2 O) 3 + CO PIR(84) H + (H 2 O) 2 (CO 2 ) + M H + (H 2 O) 2 + CO 2 + M Temperature regime not specified. PIR(85) H + (H 2 O) 2 (N 2 ) + CO 2 H + (H 2 O) 2 (CO 2 ) + N PIR(86) H + (H 2 O) 2 (N 2 ) + M H + (H 2 O) 2 + N 2 + M Temperature regime not specified. PIR(87) H + (H 2 O) 2 (N 2 ) + H 2 O H + (H 2 O) 3 + N Temperature regime not specified. PIR(88) H + (H 2 O)(CO 2 ) + H 2 O H + (H 2 O) 2 + CO PIR(89) H + (H 2 O)(CO 2 ) + M H + (H 2 O) + CO 2 + M Temperature regime not specified. PIR(90) H + (H 2 O)(N 2 ) + CO 2 H + (H 2 O)(CO 2 ) + N PIR(91) H + (H 2 O)(N 2 ) + M H + (H 2 O) + N 2 + M Temperature regime not specified. PIR(92) H 3 O + (OH) + H 2 O H + (H 2 O) 2 + OH [23] Rate coefficient was measured at 296K. PIR(93) H 3 O + (OH) + O 2 + M O + 2 (H2 O) 2 + M [24] Rate coefficient was measured at 337K for M=O 2. PIR(94) H 3 O + (OH)(H 2 O) + H 2 O H + (H 2 O) 3 + OH PIR(95) H 3 O + (OH)(CO 2 ) + H 2 O H + (H 2 O) 2 (CO 2 ) + OH PIR(96) H 3 O + (OH)(CO 2 ) + H 2 O H + (H 2 O) + OH + CO PIR(97) H + (H 2 O) 2 + N 2 O 5 HNO 3 + H + (H 2 O)(HNO 3 ) [25] PIR(98) H + (H 2 O) 3 + N 2 O 5 HNO 3 + H + (H 2 O) 2 (HNO 3 ) [25] PIR(99) H + (H 2 O) 4 + N 2 O 5 HNO 3 + H + (H 2 O) 3 (HNO 3 ) [25] PIR(100) H + (H 2 O) 5 + N 2 O 5 HNO 3 + H + (H 2 O) 4 (HNO 3 ) [25] PIR(101) H + (H 2 O) 6 + N 2 O 5 HNO 3 + H + (H 2 O) 5 (HNO 3 ) [25] PIR(102) H + (H 2 O)(HNO 3 ) + H 2 O H + (H 2 O) 2 + HNO [25] PIR(103) H + (H 2 O) 2 (HNO 3 ) + H 2 O H + (H 2 O) 3 + HNO [25] PIR(104) H + (H 2 O) 3 (HNO 3 ) + H 2 O H + (H 2 O) 4 + HNO [25] PIR(105) H + (H 2 O) 4 (HNO 3 ) + H 2 O H + (H 2 O) 5 + HNO [25] PIR(106) H + (H 2 O) 5 (HNO 3 ) + H 2 O H + (H 2 O) 6 + HNO [25] H + (CH 3 CN)(H 2 O) + H + (H 2 O) 2 PIR(107) PIR(108) PIR(109) PIR(110) PIR(111) PIR(112) PIR(113) PIR(114) PIR(115) PIR(116) H + (CH 3 CN)(HNO 3 ) + HNO [25] H + (CH 3 CN)(HNO 3 ) + H 2 O H + (CH 3 CN)(H 2 O) + HNO [25] H + (CH 3 CN)(H 2 O) 2 + N 2 O 5 H + (CH 3 CN)(H 2 O)(HNO 3 ) + HNO [25] H + (CH 3 CN)(H 2 O)(HNO 3 ) + H 2 O H + (CH 3 CN)(H 2 O) 2 + HNO [25] H + (CH 3 CN)(H 2 O) 3 + N 2 O 5 H + (CH 3 CN) (H 2 O) 2 HNO [25] H + (CH 3 CN)(H 2 O) 2 HNO 3 + H 2 O H + (CH 3 CN) (H 2 O) 3 + HNO [25] H + (CH 3 CN)(H 2 O) 4 + N 2 O 5 H + (CH 3 CN) (H 2 O) 3 HNO [25] H + (CH 3 CN)(H 2 O) 3 HNO 3 + H 2 O H + (CH 3 CN)(H 2 O) 4 + HNO [25] H + (CH 3 CN)(H 2 O) 5 + N 2 O 5 H + (CH 3 CN)(H 2 O) 4 HNO [25] H + (CH 3 CN)(H 2 O) 4 HNO 3 + H 2 O H + (CH 3 CN)(H 2 O) 5 + HNO [25] PIR(117) H + (H 2 O) + CH 3 CN H + (CH 3 CN) + H 2 O PIR(118) H + (H 2 O) 2 + CH 3 CN H + (CH 3 CN)(H 2 O) + H 2 O PIR(119) H + (H 2 O) 3 + CH 3 CN H + (CH 3 CN)(H 2 O) 2 + H 2 O PIR(120) H + (H 2 O) 4 + CH 3 CN H + (CH 3 CN)(H 2 O) 3 + H 2 O PIR(121) H + (H 2 O) 5 + CH 3 CN H + (CH 3 CN)(H 2 O) 4 + H 2 O PIR(122) H + (H 2 O) 6 + CH 3 CN H + (CH 3 CN)(H 2 O) 5 + H 2 O PIR(123) H + (H 2 O) 7 + CH 3 CN H + (CH 3 CN)(H 2 O) 6 + H 2 O PIR(124) H + (H 2 O) 8 + CH 3 CN H + (CH 3 CN)(H 2 O) 7 + H 2 O PIR(125) O + 2 (H2 O) O H 2 O NPD(1) O hv O - + O NPD(2) O hv O2 - + O NPD(3) CO hv O - + CO NPD(4) CO hv O2 - + CO NPD(5) CO - 3 (H2 O) + hv CO H 2 O PDE(1) O - + hv O + e PDE(2) O hv O 2 + e PDE(3) O hv O 3 + e PDE(4) OH - + hv OH + e PDE(5) CO hv CO 3 + e PDE(6) NO hv NO 2 + e PDE(7) NO hv NO 3 + e EDA(1) O - + O O 2 + e EDA(2) O - + NO NO 2 + e EDA(3) O - + O 2 ( 1 D g ) O 3 + e EDA(4) O - + M O + M + e EDA(5) O - + H 2 H 2 O + e Rate coefficient measured at 298K with 25% uncertainty. EDA(6) O O O 3 + e Rate coefficient measured at 298K. EDA(7) O O 2 ( 1 D g ) 2O 2 + e [26] Rate coefficient measured at 298K. EDA(8) O N 2 N 2 + O 2 + e Temperature interval is uncertain. EDA(9) O H HO 2 + e EDA(10) O O 2O 2 + e EDA(11) O O 3 3O 2 + e EDA(12) OH - + O HO 2 + e EDA(13) OH - + H H 2 O + e EDA(14) Cl - + H HCl + e NIR(1) O - + O 3 O O NIR(2) O - + 2O 2 O O [27] Rate coefficient is measured at 300K. NIR(3) O - + H 2 O OH - + OH Data is only upper limit estimation. NIR(4) O - + NO 2 NO O [28] Rate coefficient is measured at 300K. Uncertainty of measurement: 10%. NIR(5) O - + CO 2 + M CO M [15] M=O 2 Uncertainty of measurement: 30%. NIR(6) O - + H 2 OH - + H [29] NIR(7) O - + HCl Cl - + OH [15] NIR(8) O - + Cl Cl - + O NIR(9) O - + ClO Cl - + O NIR(10) O - + CH 4 OH - + CH NIR(11) O - + HNO 3 NO OH NIR(12) O - + H 2 O + M O - (H 2 O) + M [15] NIR(13) O - (H 2 O) + O 2 O H2O NIR(14) O O O - + O [30] NIR(15) O O 3 O O [15] NIR(16) O CO 2 + O 2 CO O [15] Rate coefficient is measured at 289K. M=O 2Uncertainty of measurement: 50%. Uncertainty of measurement: 40%. NIR(17) O NO 2 NO O [15] NIR(18) O O 2 + M O M [31, 32] Estimatedfor M=O 2 over the temperature range of K. Uncertainty of measurement: 15%. NIR(19) O H 2 O + M O - 2 (H2 O) + M [31, 32] Estimatedfor M=O 2 over the temperature range of K NIR(20) O HCl Cl - + HO [15] Rate coefficient is measured at 289K. NIR(21) O Cl Cl - + O NIR(22) O ClO ClO - + O NIR(23) O HNO 3 NO HO NIR(24) O 2 - (H2 O) + CO 2 CO H 2 O NIR(25) O 2 - (H2 O) + NO NO H 2 O NIR(26) O 2 - (H2 O) + O 3 O O 2 + H 2 O NIR(27) O 2 - (H2 O) + H 2 O + M O 2 - (H2 O) 2 + M NIR(28) O 2 - (H2 O) + NO 2 NO H 2 O + O NIR(29) O 2 - (H2 O) + M O H 2 O + M Temperature interval is uncertain. NIR(30) O 2 - (H2 O) 2 + M O 2 - (H2 O) + H 2 O + M Temperature interval is uncertain. NIR(31) O 2 - (H2 O) 2 + NO 2 NO 2 - (H2 O) + H 2 O + O NIR(32) O 2 - (H2 O) 2 + O 3 O 3 - (H2 O) + O 2 + H 2 O NIR(33) O O O O [15] NIR(34) O H OH - + O [15] NIR(35) O CO 2 CO O [15] NIR(36) O NO NO O [33] NIR(37) O NO 2 NO O [33] NIR(38) O H 2 O + M O 3 - (H2 O) + M NIR(39) O NO 2 NO O [33] NIR(40) O NO NO O [33] NIR(41) O 3 - (H2 O) + CO 2 CO H 2 O + O NIR(42) O 3 - (H2 O) + CO 2 CO 3 - (H 2 O) + O NIR(43) O O O O [15] NIR(44) O CO 2 CO O [15] NIR(45) O NO NO 3 - * + O [15] Uncertainty of measurement: 75%. Uncertainty of measurement: 40%. temperature range of K temperature range of K. temperature range of K temperature range of K Uncertainty of measurement: 75%. NIR(46) O H 2 O O - 2 (H2 O) + O [15] Rate coefficient estimated for 298K. NIR(47) OH - + O 3 O OH [15] Uncertainty of measurement: 75%. NIR(48) OH - + NO 2 NO OH [15] Rate coefficient is measured at 298K Uncertainty of measurement: 45%. NIR(49) OH - + CO 2 + M HCO M [15] NIR(50) OH - + HCl Cl - + H 2 O Rate coefficient estimated for 298K NIR(51) OH - + H 2 O + M OH - (H 2 O) + M [15] Uncertainty of measurement: 50%. NIR(52) OH - + Cl Cl - + OH NIR(53) OH - + ClO ClO - + OH NIR(54) CO O O CO [15] Uncertainty of measurement: 75%. NIR(55) CO O 2 O CO [33] Value is only upper limit estimation. NIR(56) CO H OH - + CO [15] Uncertainty of measurement: 40%. NIR(57) CO NO NO CO [33] NIR(58) CO NO 2 NO CO [15] NIR(59) CO HCl Cl - + OH + CO [15] Value is only upper limit estimation. NIR(60) CO H 2 O + M CO - 3 (H2 O) + M [15] Uncertainty of measurement: 50%. NIR(61) CO Cl Cl - + CO 2 + O NIR(62) CO Cl ClO - + CO NIR(63) CO ClO Cl - + CO 2 + O NIR(64) CO HNO 3 NO CO 2 + OH NIR(65) CO 3 - (H2 O) + NO NO H 2 O + CO [33] NIR(66) CO 3 - (H2 O) + NO 2 NO H 2 O + CO [33] NIR(67) CO 3 - (H2 O) + H 2 O + M CO 3 - (H2 O) 2 + M NIR(68) CO 3 - (H2 O) + NO 2 NO 3 - (H2 O) + CO NIR(69) CO 3 - (H2 O) + NO NO 2 - (H2 O) + CO Reaction not studied. Parameters are assumed to be equal to CO H 2O + M. NIR(70) CO 3 - (H2 O) + M CO H 2 O + M Temperature interval is uncertain. NIR(71) CO - 3 (H2 O) 2 + M CO - 3 (H2 O) + H 2 O + M Temperature interval is uncertain. NIR(72) CO O 3 O O 2 + CO [15] Uncertainty of measurement: 75%. NIR(73) CO H CO OH [15] Uncertainty of measurement: 40%. NIR(74) CO O CO O [15] Uncertainty of measurement: 75%. NIR(75) CO NO NO 3 *- + CO [15] NIR(76) CO H 2 O O 2 - (H2 O) + CO NIR(77) CO HCl Cl - + HO 2 + CO [15] NIR(78) CO Cl Cl - + O 2 + CO NIR(79) CO ClO ClO - + O 2 + CO NIR(80) NO H OH - + NO [15] NIR(81) NO NO 2 NO NO [15] Value is only upper limit estimation. NIR(82) NO O 3 NO O [15] Uncertainty of measurement: 40%. NIR(83) NO HCl Cl - + HNO [15] Rate coefficient is measured at 289K. NIR(84) NO Cl Cl - + NO NIR(85) NO ClO Cl - + NO NIR(86) NO HNO 3 NO HNO NIR(87) NO H 2 O + M NO 2 - (H2 O) + M [15] Uncertainty of measurement: 50%. NIR(88) NO 2 - (H2 O) + M NO H 2 O + M Temperature interval is uncertain. NIR(89) NO O NO O [15] Upper limit estimation for 298K. NIR(90) NO O 3 NO O [15] Upper limit estimation for 298K. NIR(91) NO H 2 O + M NO 3 - (H2 O) + M [34] Rate coefficient is measured at 300K. NIR(92) NO HCl Cl - + HNO [15] Upper limit estimation for 298K. Rate coefficient is measured over the NIR(93) NO HCl + M NO - 3 (HCl) + M [35] temperature range of K. Uncertainty of measurement: 30-50% NIR(94) NO HNO 3 + M NO 3 - (HNO3 ) + M NIR(95) NO 3 - (H2 O) + M NO H 2 O + M [4] NIR(96) NO 3 - (H2 O) + H 2 O + M NO 3 - (H2 O) 2 + M NIR(97) NO - 3 (H2 O) + N 2 O 5 NO - 3 (HNO3 ) + HNO NIR(98) NO - 3 (H2 O) 2 + M NO - 3 (H2 O) + H 2 O + M NO 3 - (H2 O) 2 + N 2 O 5 Reaction not studied. Parameters are assumed to be equal to NO H 2O + M. NIR(99) NO 3 - (HNO3 ) + HNO 3 + H 2 O NIR(100) NO - 3 (H2 O) + HNO 3 NO - 3 (HNO3 ) + H 2 O NIR(101) NO - 3 (HNO3 ) + M NO HNO 3 + M NIR(102) NO - 3 (HNO3 ) + HNO 3 + M NO - 3 (HNO3 ) 2 + M NIR(103) NO - 3 (HNO3 ) 2 + M NO - 3 (HNO3 ) + HNO 3 + M NIR(104) NO 3 - (HCl) + HNO3 NO 3 - (HNO3 ) + HCl NIR(105) NO 3 - * + CO2 CO NO NIR(106) NO 3 - * + H NO2 - + OH NIR(107) NO 3 - * + NO NO2 - + NO NIR(108) NO 3 - * + HCl Cl - + HNO NIR(109) NO 3 - * + Cl Cl - + NO + O NIR(110) NO 3 - * + ClO Cl - + NO 2 + O NIR(111) HCO Cl Cl - + OH + CO NIR(112) HCO ClO Cl - + HO 2 + CO NIR(113) Cl - + NO 2 NO Cl [15] NIR(114) Cl - + H 2 O + M Cl - (H 2 O) + M [15] NIR(115) Cl - + HNO 3 NO HCl Data is only upper limit estimation for 298K. Data is only upper limit estimation for 298K.Uncertainty of measurement: 50% NIR(116) Cl - + CO 2 + M Cl - (CO 2 ) + M [4] NIR(117) Cl - + HCl + M Cl - (HCl) + M NIR(118) Cl - (H 2 O) + M Cl - + H 2 O + M [15] NIR(119) Cl - (H 2 O) + HCl Cl - (HCl) + H 2 O [36] Rate coefficient measured only at 298K. NIR(120) Cl - (CO 2 ) + M Cl - + CO 2 + M [4] NIR(121) Cl - (HCl) + M Cl - + HCl + M NIR(122) ClO - + NO Cl - + NO NIR(123) ClO - + NO Cl + NO NIR(124) ClO - + O Cl - + O Due to the lack of available data, the same IIR 7 X + + Y - Products values are estimated to all ion-ion reactions. References 1. Turunen, E., H. Matveinen, J. Tolvanen, and H. Ranta, D-region ion chemistry model. Handbook of Ionospheric Models, ed. R.W. Schunk. 1996, Boulder, Colorado: SCOSTEP Secr. 2. Sheehan, C.H., St.-Maurice, J-P., Dissociative recombination of N 2 +, O 2 +, and NO + : rate coefficients for ground state and vibrationally excited ions. J.Geophys.Res., (3): p Petrignani, A., Andersson, P.U., Pettersson, J.B.C., Thomas, R.D., Hellberg, F., Ehlerding, A., Larsson, M., van der Zand

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